准噶尔盆地滴南凸起白垩系清水河组层序地层划分及沉积特征

准噶尔盆地滴南凸起是陆东地区重要的油气聚集区带,其油气源条件优越,储盖配置良好,已于石炭系—白垩系多个层系获得工业油气流,但对其白垩系的研究尚欠深入。为此,以层序地层学理论为指导,基于地震资料和60口探井的录井、测井资料,对滴南凸起白垩系清水河组进行详细的地层对比及划分,进而分析其层序地层特征、沉积特征及演化。研究结果表明,研究区清水河组自下而上可划分为清一段、清二段、清三段、清四段和清五段,且清一段—清四段发育的底砾岩层具有穿时的现象;清水河组可划分为1个三级层序,由下至上发育的低位体系域、湖侵体系域和高位体系域构成了一套完整的湖平面变化周期;在平面上可识别出辫状河三角洲相和湖泊相,以及物源方向由西北至东部的变化。研究区辫状河三角洲相良好的储集条件与底砾岩层的穿时分布为地层和岩性油气藏的形成提供了有利条件,沿清一段—清四段4条超覆尖灭带分布的底砾岩层可成为下步油气勘探的有利目标。     

Dandelion-Like Bi2S3/rGO hierarchical microspheres as high-performance anodes for potassium-ion and half/full sodium-ion batteries

Sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs) have been considered as attractive alternatives for next-generation battery systems, which have promising application potential due to their earth abundance of potassium and sodium, high capacity and suitable working potential, however, the design and application of bi-functional high-performance anode still remain a great challenge up to date. Bismuth sulfide is suitable as anode owing to its unique laminar structure with relatively large interlayer distance to accommodate larger radius ions, high theoretical capacity and high volumetric capacity etc. In this study, dandelion-like Bi₂S₃/rGO hierarchical microspheres as anode material for PIBs displayed reversible capacity, and 206.91 mAh·g⁻¹ could be remained after 1,200 cycles at a current density of 100 mA·g⁻¹. When applied as anode materials for SIBs, 300 mAh·g⁻¹ could be retained after 300 cycles at 2 A·g⁻¹ and its initial Coulombic efficiency is as high as 97.43%. Even at high current density of 10 A·g⁻¹, 120.3 mAh·g⁻¹ could be preserved after 3,400 cycles. The Na₃V₂(PO₄)₃@rGO//Bi₂S₃/rGO sodium ion full cells were successfully assembled which displays stable performance after 60 cycles at 100 mA·g⁻¹. The above results demonstrate that Bi₂S₃/rGO has application potential as high performance bi-functional anode for PIBs and SIBs.

     

多组元钛合金电子束冷床炉熔炼挥发规律研究

利用电子束冷床炉(EB炉)一次熔炼制备TC4、Ti6242、TA15钛合金铸锭,采用Langmuir定律对熔炼过程中Al、Sn、Zr、Mo等元素的挥发规律做了简要的数值分析,并与实际挥发规律进行了对比分析。结果表明:EB炉熔炼TC4、Ti6242、TA15钛合金过程中,Al元素在3种合金中的挥发率有所不同,挥发率由大到小顺序为TC4>Ti6242>TA15;Al元素是TC4钛合金中主要的挥发元素;Ti6242钛合金中,Al、Sn元素之间存在联合挥发的问题;TA15钛合金中,Al、Zr元素之间亦存在联合挥发的问题,Al元素带动了Zr元素(难挥发元素)的挥发。     

Unveiling the role of Fe3O4in polymer spin valve near Verwey transition

The spinterface formed between ferromagnetic(FM)electrode and organic materials is vital for performance optimization in organic spin valve(OSV).Half-metallic Fe₃O₄with drastic change in structure,conductivity and magnetic property near Verwey transition can serve as an intrinsic spinterface regulator.However,such modulating effect of Fe₃O₄in OSV has not been comprehensively investigated,especially below the Verwey transition temperature(Tv).Here,we highlight the important role of Fe₃O₄electrode in reliable-working and controllable Fe₃O₄/P3HT/Co polymer spin valves by investigating the magnetoresistance(MR)above and below 7V.In order to distinguish between different contributions to charge transport and related MR responses,the systematic electronic and magnetic characterizations were carried out in full temperature range.Particularly,the first-order metal-insulator transition in Fe₃O₄has a dramatic effect on the MR enhancement of polymer spin valves at 7V.Moreover,both the conducting mode transformation and MR line shape modulation could be accomplished across 7V.This research renders unique scenario to multimodal storage by external thermodynamic parameters,and further reveals the importance of spin-dependent interfacial modification in polymer spin valves.